Energy storage materials derived from Prussian blue analogues
نویسندگان
چکیده
منابع مشابه
Synthesis and Structure of Prussian Blue Analogues
The Electrochemical Society Interface • Fall 2002 olecular magnetism is an evolving discipline relying on quantum chemistry, orbitals and Hamiltonians, organic and coordination chemistries, physics, and devices. Among the exciting molecule-based magnetic systems, Prussian blue analogues occupy a peculiar position. Prussian blue itself was described for the first time in 1704. Since this time, t...
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Mixed-valence polycyanides (Prussian Blue analogues) possess a rich palette of properties spanning from room-temperature ferromagnetism to zero thermal expansion, which can be tuned by chemical modifications or the application of external stimuli (temperature, pressure, light irradiation). While molecule-based materials can combine physical and chemical properties associated with molecular-scal...
متن کاملThe role of vacancies in the hydrogen storage properties of Prussian blue analogues
The porosity and hydrogen storage properties of the dehydrated Prussian blue type solids Ga[Co(CN)6], Fe4[Fe(CN)6]3, M2[Fe(CN)6] (M = Mn, Co, Ni, Cu), and Co3[Co(CN)5]2 are reported and compared to those of M3[Co(CN)6]2 (M = Mn, Fe, Co, Ni, Cu, Zn). Nitrogen sorption measurements suggest partial framework collapse for M2[Fe(CN)6] (M = Co, Ni) and Co3[Co(CN)5]2, and complete collapse for Mn2[Fe(...
متن کاملVacancy-driven magnetocaloric effect in Prussian blue analogues
We experimentally show that the magnetocaloric properties of molecule-based Prussian blue analogues can be adjusted by controlling during the synthesis the amount of intrinsic vacancies. For CsxNi II 4 [Cr (CN)6](8+x)/3, we find indeed that the ferromagnetic phase transition induces significantly large magnetic entropy changes, whose maxima shift from∼ 68 K to∼ 95 K by varying the number of [Cr...
متن کاملNew Magnetic Functionalities Presented by Prussian Blue Analogues
The Electrochemical Society Interface • Fall 2002 olecular magnetism has been one of the active areas in molecular chemistry for the last 15 years.1-6 The advantages of molecule-based magnets compared to classical metal and metal oxide ones are that the magnets can be obtained through a selection of proper spin sources (e.g., transition metal ions, organic radicals) and coordinating ligands. On...
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ژورنال
عنوان ژورنال: Science Bulletin
سال: 2017
ISSN: 2095-9273
DOI: 10.1016/j.scib.2017.01.030